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Ricinoleic Acid vs. Oleic Acid Comparison

Comparison Table: Ricinoleic Acid vs. Oleic Acid

Property Ricinoleic Acid Oleic Acid
Chemical Structure Monounsaturated fatty acid with a hydroxyl group (-OH) Monounsaturated fatty acid without a hydroxyl group
Formula C18H34O3 C18H34O2
Double Bonds One double bond (C=C) between the 9th and 10th carbon One double bond (C=C) between the 9th and 10th carbon

Spectral Comparison:

When comparing the infrared (IR) spectra of ricinoleic acid and oleic acid, some distinct differences can be observed due to the presence of the hydroxyl group in ricinoleic acid.

  • Ricinoleic Acid IR Spectrum:
    • The IR spectrum of ricinoleic acid exhibits a broad and strong absorption band around 3400 cm^-1, which corresponds to the O-H stretching vibration of the hydroxyl group.
    • A characteristic peak is observed around 1700 cm^-1, representing the C=O stretching vibration in the carboxylic acid group.
  • Oleic Acid IR Spectrum:
    • In the IR spectrum of oleic acid, the absence of the hydroxyl group results in the absence of the strong O-H stretching band around 3400 cm^-1, which is a distinguishing feature from ricinoleic acid.
    • Similarly, the C=O stretching vibration peak is observed around 1700 cm^-1.

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